The unusual self-organising behaviour of a glycosteroidal bolaphile.

نویسندگان

  • Fahima Ali Rachedi
  • Stéphane Chambert
  • Fouad Ferkous
  • Yves Queneau
  • Stephen J Cowling
  • John W Goodby
چکیده

In this communication we report on the self-organising properties of a novel asymmetric bolaphile composed of sugar and steroidal units. The material was found to exhibit unusual phase changes in that it formed a cubic phase upon heating, whereas upon cooling it formed a lamellar phase. This change in property was ascribed to kinetic versus thermodynamic behaviour at the phase transition to the liquid.

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عنوان ژورنال:
  • Chemical communications

دوره 42  شماره 

صفحات  -

تاریخ انتشار 2009